松岡 秀人
  マツオカ ヒデト   MATSUOKA Hideto
   所  属   釧路校
   職  名   准教授
言語種別 英語
発行・発表の年月 2016
形態種別 学術雑誌
査読 査読あり
標題 High-Frequency EPR Studies on Polymer Chain Morphology in Dip-Coated Films of Poly(3-hexylthiophene)/Fullerene Bulk-Heterojunctions
執筆形態 共著第一著者
掲載区分国外
出版社・発行元 公益社団法人 日本化学会
巻・号・頁 89(3),pp.378-384
担当区分 筆頭著者,責任著者
著者・共著者 Matsuoka Hideto, Mizutani Shinichi, Watanabe Chika, Yamauchi Seigo
概要 Polymer chain morphology and its response to annealing were investigated in terms of g-tensor anisotropy in poly(3-hexylthiophene) (P3HT)/fullerene blend films fabricated by dip coating. The g-anisotropy highly resolved by W-band (94 GHz) electron paramagnetic resonance (EPR) spectroscopy enabled us to precisely determine the molecular orientation of P3HT. The substrate dependence of the morphology was also investigated by W-band EPR spectroscopy. The determined morphology and EPR line width provided insight into the growth of P3HT crystalline domains, which was correlated with solar cell performance.
DOI 10.1246/bcsj.20150400
ISSN 00092673
NAID 130005137568