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松岡 秀人
マツオカ ヒデト MATSUOKA Hideto 所 属 釧路校 職 名 准教授 |
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| 言語種別 | 英語 |
| 発行・発表の年月 | 2018/12/14 |
| 形態種別 | 学術雑誌 |
| 査読 | 査読あり |
| 標題 | ESR analyses of picket fence Mn^II and 6th ligand coordinated Fe^III porphyrins (S = 5/2) and a Co^II(hfac) complex (S = 3/2) with sizable ZFS parameters revisited: A full spin Hamiltonian approach and quantum chemical calculations |
| 執筆形態 | 共著 |
| 掲載誌名 | Dalton Transactions |
| 掲載区分 | 国外 |
| 出版社・発行元 | Royal Society of Chemistry |
| 巻・号・頁 | 47(46),pp.16429-16444 |
| 著者・共著者 | Yamane, Takeshi, Sugisaki, Kenji, Matsuoka, Hideto, Sato, Kazunobu, Toyota, Kazuo, Shiomi, Daisuke, Takui, Takeji |
| 概要 | The fictitious spin-1/2 (effective spin-1/2) spin Hamiltonian approach is the putative method to analyze the conventional fine-structure/hyperfine ESR spectra of high spin metallocomplexes with sizable zero-field splitting (ZFS) tensors since early in 1950's, and the approach gives salient principal g^eff-values far from g = 2 without explicitly affording their ZFS values in most cases. The experimental g^eff-values thus determined, however, never agree with those (g^true-values) of the true principal g-tensors, which are obtainable form reliable quantum chemical calculations.... |
| DOI | 10.1039/c8dt02988a |
| ISSN | 14779226 |
| NAID | 120006776860 |