中村 秀夫
  ナカムラ ヒデオ   NAKAMURA Hideo
   所  属   函館校
   職  名   教授
言語種別 英語
発行・発表の年月 2011/11
形態種別 学術雑誌
査読 査読あり
標題 Application of MgO and CaO covered with Al2O3 in alkylation of malonate
執筆形態 共著
掲載誌名 Journal of the Japan Petroleum Institute
出版社・発行元 Society of Japan Petroleum Institute
巻・号・頁 54(6),pp.385-389
著者・共著者 Y. Sakamoto, H. Matsuhashi, and H. Nakamura
概要 Recently developed solid bases of MgO and CaO covered with Al2O3 was applied to an alkylation of malonate with several kinds of alkyl halides. Diethyl malonate was converted into mono-alkylated and/or di-alkylated malonate by these solid bases without solvent. Prepared solid bases showed higher activity than unmodified MgO and CaO. Al2O3/MgO gave the mono-alkylated malonates in high selectivity.